Reaction Dynamics of Gas-Phase Transition Metal Atoms
نویسندگان
چکیده
منابع مشابه
Gas-phase activation of methane by ligated transition-metal cations.
Motivated by the search for ways of a more efficient usage of the large, unexploited resources of methane, recent progress in the gas-phase activation of methane by ligated transition-metal ions is discussed. Mass spectrometric experiments demonstrate that the ligands can crucially influence both reactivity and selectivity of transition-metal cations in bond-activation processes, and the most r...
متن کاملThe Gas Phase Oxidation of Acetaldehyde Reaction Mechanism and Kinetics
The mechanism of the low temperature oxidation of gaseous acetaldehyde was investigated in the temperature range of 1 50-400?°C. The minor, intermediate and major products were identified and measured quantitatively by sampling directly into the ionization chamber of an MS10-C2 mass spectrometer from the reactor. The formation of H2O, CO, CO2, HCOOH, H2, HCHO, CH3COOH and CH3OH as the major pro...
متن کاملDynamics of Reaction of Monoenergetic Atoms
When monoenergetic atoms are continuously introduced into a thermal gas, they can undergo deactivating, activating, and reactive collisions. The net result of such collisions is to establish a steady-state distribution of laboratory energies which, although not as sharp as the initial distribution, preserves some of its features, such as being centred at about the initial energy. The reactive c...
متن کاملThe nuclear liquid–gas phase transition within Fermionic Molecular Dynamics
The time evolution of excited nuclei, which are in equilibrium with the surrounding vapour, is investigated. It is shown that the finite nuclear systems undergo a first oder phase transition. The caloric curve is presented for excited O, Mg, Al and Ca and the critical temperature is estimated for O. PACS: 24.10.Cn, 02.70.Ns, 05.30.-d, 05.30.Fk, 05.60.+w, 05.70.Fh
متن کاملEnergy Spectrum and Phase Transition of Superfluid Fermi Gas of Atoms on Noncommutative Space
Based on the Bogoliubov non-ideal gas model, we discuss the energy spectrum and phase transition of the superfluid Fermi gas of atoms with a weak attractive interaction on the canonical noncommutative space. Because the interaction of a BCS-type superfluid Fermi gas originates from a pair of Fermionic quasi-particles with opposite momenta and spins, the Hamiltonian of the Fermi gas on the nonco...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Molecular Science
سال: 2008
ISSN: 1881-8404
DOI: 10.3175/molsci.2.a0025